News and Trends

http://www.ethanolproducer.com/article.jsp?article_id=3728
http://minnesota.publicradio.org/display/web/2008/02/04/biofuelsstudy/

Cellulose-based plant biomass (such as switch grass and other perennial grasses) is considered a “second generation” biofuel crop, and is thought of as “the way to go” for the production of ethanol for biofuel applications. In contrast to “first generation” bioenergy crops (such as corn), the use of cellulosic feedstocks for ethanol production are said to require lesser agricultural inputs, have better net energy yields and have better “carbon balances”. Many farmers in the United States are considering a shift from corn/soya to perennial grasses as biofuel feedstocks. This shift in bioenergy crop, however, can have effects on the “seasonal cycle of water and energy exchanges between the land and the lower portion of the atmosphere”. A joint research collaboration between South Dakota University’s Geographic Information Science Center of Excellence and the National Aeronautics and Space Agency (NASA) (United States) will attempt to assess the impacts of this bioenergy crop shift on weather and climate. The three year study will use field and modeling approaches to evaluate potential impacts of the biofuel crop shift in a study area covering North Dakota, South Dakota, Nebraska, western Minnesota and northern Iowa. According to Senior Scientist Michael Wimberly, the goal is not make exact predictions, but rather “to make broad but reasonable assumptions, so potential consequences can become part of the discussion”..


http://www.fao.org/newsroom/en/news/2008/1000782/index.html
http://biopact.com/2008/02/fao-unveils-important-bioenergy.html

The United Nations Food and Agriculture Organization (UN-FAO) has announced the development of a “decision-support tool” to help countries derive the benefits of biofuel industry development, without putting food security at risk. According to the FAO press release, the tool is an “analytical framework” and can allow governments venturing into biofuels to “calculate the effect of their [biofuel-related] policy decisions on the food security of their populations”. The initial step for using the framework involves the establishment of a “bioenergy scenario”, where the biofuel policy options and associated strategies are defined. The framework allows a five-step assessment of (1) technical biomass potential, (2) biomass production costs, (3) the economic bioenergy potential, (4) macro-economic consequences, and (5) national and household-level impact and consequences on food security. The analytical framework which uses mathematical models like “Quickscan” from the Copernicus Institute (at the University of Utrecht, Netherlands) and “COSIMO” from FAO, will be field-tested in Peru, Thailand and Tanzania before release..


http://www.gatech.edu/newsroom/release.html?id=1707
http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6V2P-4RJ4KCY-2&_user=10&_coverDate=01%2F08%2F2008&_alid=688196265&_rdoc=1&_fmt=summary&_orig=search&_cdi=5708&_sort=d&_docanchor=&view=c&_ct=1&_acct=C000050221
&_version=1&_urlVersion=0&_userid=10&md5=ddb5d3a87a62a7435ec3891db6ed365c
(may require paid subscription for complete access)

Carbon Capture and Storage (CCS) technology (involving the collection and transport of CO2 emissions for ultimate geological or ocean storage), is a climate-change mitigation strategy usually tailored for large scale emission sources, like power plants. However, about two-thirds of global CO2 emissions are said to be from small scale “distributed” sources, like automobiles and small power plants. A CCS technology tailored to such small scale distributed CO2 sources would contribute much for mitigating climate change by reducing CO2 emissions. American researchers from the Georgia Institute of Technology (Georgia Tech), have conceptualized a CCS system for these small scale distribution sources. According to the Georgia Tech press release, the Georgia Tech team’s goal is to develop a “sustainable transportation system” which uses liquid fuel, and traps/stores the carbon dioxide emitted using an on-board device. The stored CO2 can then be dropped off to a processing plant where it can be recycled into liquid fuel. Under development is the on-board fuel processing device “to separate the carbon and store it in the vehicle in liquid form”. The conceptual study is published in the journal, Energy Conversion and Management (URL above).

Related information on Carbon Capture and Storage Technology: http://en.wikipedia.org/wiki/Carbon_capture_and_storage

Biofuels Processing

http://news-info.wustl.edu/tips/page/normal/10782.html

Butanol is considered an “advanced biofuel” and is said to have several advantages over ethanol, like its higher energy density, lower water affinity and lesser corrosion capacity. Companies like Dupont and BP have jumped into the “butanol bandwagon” to produce butanol using saccharine materials like sugar beets. Recently, a research team from Washington University in St Louis and the United States Department of Agriculture (USDA), are developing a sequential process to produce butanol from a more abundant resource, lignocellulosic biomass (like corn fiber). The sequential process involves the (1) pretreatment of the lignocellulosic biomass to make it amenable to microbial attack, (2) anaerobic digestion of pretreated biomass for conversion to butyrate (a four-carbon acid) by a mixed culture of microorganisms, and (3) fermentation of butyrate to butanol. The team from the USDA will do the pretreatment and butanol fermentation part, while the team from Washington University (headed by environmental engineer, Lars Argenent), will do the mixed culture anaerobic digestion part..


http://pubs.acs.org/cgi-bin/abstract.cgi/iecred/2007/46/i03/abs/ie061202s.html
http://dodfuelcell.cecer.army.mil/library_items/DCFC_Report.pdf
http://biopact.com/2008/02/closer-look-at-direct-carbon-fuel-cells.html

Fuel cells are essentially “batteries” which generate electricity as a result of chemical reactions of the raw materials that occur at the positive electrode (cathode) and at the negative electrode (anode). It is considered one of the “green technologies” for electrical power generation. The conventional industrial fuel cells utilize gaseous raw materials (hydrogen at the cathode, and oxygen at the anode) to drive the electricity generating reaction (hydrogen + oxygen = water). The hydrogen source can be from the thermochemical processing of biomass. Recently, however, a new type of fuel cell technology (called “Direct Carbon Fuel Cell Technology”), utilizes solid carbon at the cathode, instead of hydrogen. Solid carbon (“char”, “charcoal”, or “biocoal”) is the residue from the oxygen-free thermochemical processing of the biomass (also called “pyrolysis”). In the new process, the carbon is dissolved in molten salt and provides the raw material at the cathode. Oxygen is provided as the raw material at the anode, and the electricity generating reaction is: carbon+oxygen= carbon dioxide. The main advantage of the new fuel cell technology is said to be its higher energy efficiency of about 80%, compared to only 30% to 60% in conventional fuel cells. Other advantages include: (1) the versatility in the use of any abundant carbonaceous material, and (2) no costly catalyst needed..


http://www.utwente.nl/nieuws/pers/en/cont_08-007_en.doc/
http://www.rsc.org/delivery/_ArticleLinking/DisplayHTMLArticleforfree.cfm?JournalCode=CC&Year=2008&ManuscriptID=b718082a&Iss=Advance_Article

Although ethanol is produced by the fermentation of biomass-derived sugars, the ethanol in the fermentation broth (roughly about 3% to 10% by volume) must be ultimately separated and purified in a water-free form (99.99% purity), in order to be used in gasoline blends. Traditionally, the separation of ethanol from the fermentation broth involves an energy-intensive step of distillation. During distillation (a major cost component in ethanol production), the broth is heated to boiling to vaporize the ethanol and the ethanol vapor goes to a condenser where it it condensed back to its liquid form. The use of membranes to separate ethanol from fermentation broths, are said to have lower energy costs compared to distillation, but its major drawbacks are the durability and stability of the membranes. Conventional inorganic ceramic membranes are said to be easily degraded on long exposure to water. Recently however, a new type of hybrid inorganic-organic type of ceramic membrane has been developed from scientists at the University of Twente (Netherlands). The membranes were found to be effective in separating and drying biofuels with “unprecedented hydrothermal stability”, enabling “energy-efficient” molecular separations up to 150 oC. A report about the description and performance of the membrane can be found at the Chemical Communications website (URL above)..

Biofuels Policy and Economics

http://www.sciencemag.org/cgi/content/abstract/1152747
(full access to paper may require paid subscription)
http://biopact.com/2008/02/two-studies-state-obvious-clearing-high.html

A recent article from the journal, Science, says that the carbon savings offered by low carbon biofuel crops (like corn for ethanol or soya for biodiesel) depend on how the biofuel is produced. Their studies have shown that conversion of “high carbon storage” forests and grasslands for biofuel crop plantations could actually cause a net increase in carbon dioxide emissions, resulting in a “carbon debt”. Estimates show that the conversion of peatlands to palm oil plantations would incur a carbon debt of about 423 years in Malaysia and Indonesia, before the lands could begin to recover and reduce greenhouse gas levels. In South America, the conversion of Amazon rainforest to soya plantations for biodiesel has been estimated to have a carbon debt of 319 years. However, biofuels made from perennials (i.e. grasses) grown in marginal or abandoned agricultural lands would result in “little or no carbon debt”, and could offer “sustained GHG (greenhouse gas) advantages”. Details of their study can be obtained from the Science journal website (URL above)..


http://www.sciencemag.org/cgi/content/abstract/1151861
(full access to paper may require paid subscription)
http://biopact.com/2008/02/two-studies-state-obvious-clearing-high.html

An article from the journal, Science, points out that when making carbon balances for biofuel production, one must account not only the carbon that is sequestered from the growth of the biofuel crop, but also other factors that result in carbon emissions. These factors include those resulting from the conversion of food lands to biofuel crop plantations. Using a “worldwide agricultural model”, researchers assessed that U.S. corn ethanol actually increases carbon emissions. Estimates show the carbon emissions would double in 30 years and the increase would continue for about 167 years. Their study raises second thoughts about large scale land conversions for biofuels. Details of their research can be obtained from the Science journal website (URL above)..