
DMF (2,5-dimethylfuran) Produced from Biomass-Derived Sugar is Biofuel Alternative to Ethanol
July 27, 2007http://www.nature.com/nature/journal/v447/n7147/abs/nature05923.html
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Researchers from University of Wisconsin-Madison in the United States have developed a process for producing a biofuel with better properties than ethanol. In a recent issue of the journal Nature, Chemical and Biological Engineering Professor James Dumesic and his team reported the “production of dimethylfuran for liquid fuels from biomass-derived carbohydrates”. The process starts with the chemical conversion of the raw material (a 5-carbon sugar called fructose) to HMF (hydroxymethylfurfural) using an acid catalyst in the presence of a low boiling point solvent. The solvent extracts the HMF from the reaction mixture for processing in the next step, which is the conversion of HMF to DMF, using a copper-based catalyst. The final biofuel product, DMF, is said to contain the following improvements over ethanol: (1) 40% higher energy density, (2) higher boiling point (i.e., DMF is less volatile and remains liquid in the fuel tank, and vapour in the engine, and (3) does not absorb water..
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