
US Scientists Develop Single Step Cellulose Conversion to Biofuel Platform Chemical
May 29, 2009http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TF5-4W1JW05-1&_user=10&_rdoc=1&_fmt=&_orig=search&_sort=d&view=c&_acct=C000050221&_
version=1&_urlVersion=0&_userid=10&md5=7405c85e8bdba3dc0ed33c5ff3ed3a2b
http://www.thebioenergysite.com/news/3785/raw-material-for-fuels-and-plastic-from-plants
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Scientists from the Pacific Northwest National Laboratory (PNNL) of the United States Department of Energy (US-DOE), reports a single step conversion of cellulosic biomass into a useful organic "platform chemical", called HMF. Their study is published in the journal, Applied Catalysis A (URL above). As a "platform chemical", HMF (or 5-hydroxymethylfurfural) can be further processed into plastic or synthetic liquid biofuels. Conventionally, HMF can be produced from sugars, but PNNL scientists recently found a way to produce it from cellulosic biomass through a two step conversion: "cellulose-to-sugars-to-HMF". They were able to go one step further by doing away with the cellulose-to-sugar step by using paired catalysts (CuCl2/CrCl2 in organic solvent) to develop a direct "cellulose-to-HMF" process. According to the scientists, "the ability to synthesize HMF directly from raw natural cellulose [in a single step] would remove a major barrier to the development of a sustainable HMF platform".
Related information on HMF: http://en.wikipedia.org/wiki/Hydroxymethylfurfura
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