
Process Converts Any Lipid-based Raw Material to Aviation Biofuels
April 12, 2007http://news.ncsu.edu/releases/2007/feb/031.html
http://www.diversified-energy.com/auxfiles/centia/CentiaExecutiveSummary.pdf
http://www.insidegreentech.com/node/739
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Engineers from North Carolina State University (NCSU) and Diversified Energy Corporation (DEC) in the United States are testing a patent-pending process which can convert any lipid-based raw material (oils or fats derived from plant or animal sources) into high value aviation biofuel (for jet engines) or additives for cold-weather biofuels. New advantages of the process is that even low quality lipid products like cooking grease can be used, and that there are no more disposal problems associated with the waste by-product, glycerol. Aviation biofuels have more stringent requirements for energy density, combustion, and cold flow properties than traditional biofuels. The process (called “CentiaTM), involves a three-step thermo-catalytic reforming process. In the first stage (called hydrolysis), the feedstock is subjected to high temperature and pressure to strip off the free fatty acids (FFA) from the glycerol backbone of the lipid. The glycerol waste by-product is burned off for energy, while the FFA enters the second step. In the second stage (the decarboxylation step), the FFA’s and a solvent are heated under pressure with a catalyst to remove carbon dioxide, resulting in the formation of straight chain hydrocarbons (called “alkanes”) that are 15 or 17 carbon atoms (C15 or C17) long. The aviation biofuel is then produced in the third step (the reforming step), where the straight chained C15 or C17 alkanes are reformed into branched “iso-alkanes” containing 10 to 14 carbon atoms. So far, this is said to be the first process ever to produce a biofuel that is jet-compliant. The team is currently furthering the maturity of the technology and is “seeking investors and strategic partners for full-scale bench testing, pilot plant development, feedstock supply, and fuels purchase agreements.”.
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